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To create and configure a new connection, open "Network ans Sharing Center" → "Set up a new connection or network".
In the window that opens, select "Manually connect to a wireless network" and click "Next".
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Check the "Start this connection automatically". Click "Next".
The network has been successfully added. Next, configure the connection settings.
Open the "Security" section, select the authentication method "Microsoft: Smart Card or other certificate (EAP-TLS)". Click "Settings".
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In the opened window choose "Advanced settings".
Specify the authentication mode – "Usar User authentication". Click "ОК".
Find the desired network and click "Connect". Select the user certificate to connect to the network and enter the user login. Click "ОК".
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If the parameters are entered correctly, the connection will be successful.
Connecting with Ubuntu
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